《无机化学》（第2版） (张祖德)pdf电子书下载

目次
总序 i
前言 iii
第 1部分化 学 原 理Part 1Chemical Principles
第1章 气体、液体和溶液的性质 3
Chapter 1 The Behaviors of Gas,Liquid and Solution 3
1.1 气体的性质 3
The Properties of Gases 3
1.2 液体17
Liquids 17
1.3 溶液23
Solutions 23
第2章 化学热力学基础与化学平衡 38
Chapter 2 The Basis of Chemical Thermodynamics and Chemical
Equilibrium38
2.1 化学热力学的体系与状态38
System and State of Chemical Thermodynamics 38
2.2 热力学第一定律42
First Law of Thermodynamics 42
2.3 热化学47
Thermochemistry 47
2.4 热力学第二定律51
无机 化 学
Second Law of Thermodynamics 51
2.5 化学平衡61
Chemical Equilibrium 61
第3章 酸碱理论与电离平衡 71
Chapter 3 The Theories of Acids & Bases and lonization Equilibrium71
3.1 酸碱理论71
The Theories of Acids and Bases 71
3.2 弱酸弱碱的电离平衡77
The lonic Equilibrium of Weak Acids and Weak Bases 77
3.3 盐的水解89
The Hydrolysis of Salts 89
第4章 沉淀反应 92
Chapter 4 The Precipitation Reactions 92
4.1 溶度积92
Solubility Product 92
4.2 沉淀-溶解平衡的移动 95
Equilibrium Shift between Precipitation and Dissolution 95
4.3 多种沉淀之间的平衡97
Equilibrium in Many Precipitants 97
第5章 氧化-还原反应和电化学 104
Chapter 5 Oxidation-Reduction Reaction and Electrochemistry 104
5.1 氧化-还原反应104
Oxidation-Reduction Reaction 104
5.2 电极电势 111
Electrode Potential 111
5.3 电极电势的应用 124
Applications of Electrode Potential 124
第6章 化学动力学基础131
Chapter 6 The Basis of Chemical Dynamics 131
6.1 化学反应速率 131
The Rate of Chemical Reaction 131
6.2 化学反应机理 154
Reaction Mechanism 154
目次
第2部分 化 学 理 论
Part 2Chemical Theories
第7章 原子结构和元素周期律163
Chapter 7 The Atomic Structure and Periodic System of Elements 163
7.1 原子内部的发现 164
Discovery of Structure in Atom 164
7.2 氢原子光谱和能级的概念 170
The Spectrum of Atomic Hydrogen and Concept of Energy Levels
170
7.3 原子核外电子的运动状态 177
Moving Stations of Electrons outer the Atomic Nucleus 177
7.4 多电子原子结构和周期系 185
Structure in Many-Electron Atoms and Periodic System 185
7.5 元素基本性质的周期性 195
Periodic Properties of the Elements 195
第8章 化学键和分子、晶体结构 202
Chapter 8 Chemical Bonds and Structures of Molecules & Crystals 202
8.1 共价键与分子几何构型 202
Covalent Bond and Molecular Geometric Structure 202
8.2 金属键与金属晶体 232
Metallic Bond and Metallic Crystal232
8.3 离子键与离子晶体 243
lonic Bond and lonic Crystal 243
8.4 晶体学基础 257
Basic Crystallology 257
第9章 配位化合物267
Chapter 9 The Coordination Compounds 267
9.1 配合物的基本概念 268
Basic Concepts of Coordination Compounds 268
9.2 配位化合物的异构现象 279
无机 化 学
Isomerism of Coordination Compounds 279
9.3 配合物的化学键理论 298
The Chemical Bond Theories of Complexes 298
9.4 配位平衡及配合物的稳定性 315
Coordination Equilibrium and Stabilization of Complex 315
9.5 配位化合物的应用 322
Application of Coordination Compounds 322
第3部分描 述 化 学
Part 3 Descriptive Chemistry
s区和 p区元素化学引言 331
Introduction of the Chemistry of s and p Elements 331
第10章 稀有气体 334
Chapter 10 The Rare Gases 334
10.1 稀有气体的通性334
General Properties of Rare Gases 334
10.2 氙的化学338
Chemistry of Xenon 338
第11章 氢、碱金属和碱土金属345
Chapter 11 Hydrogen, Alkali and Alkali-earth Metals 345
11.1 氢及其化合物345
Hydrogen and Its Compounds 345
11.2 碱金属元素及其化合物351
Alkali Metals and Their Compounds 351
11.3 碱土金属及其化合物358
Alkali-earth Metals and Their Compounds 358
11.4 专题讨论366
Discussion of Special Subjects 366
第 12章 卤素 369
Chapter 12 The Halogens 369
12.1 氟及其化合物370
目次
Fluorine and Its Compounds 370
12.2 氯及其化合物374
Chlorine and Its Compounds 374
12.3 溴分族380
Bromine Subgroup 380
12.4 拟卤素和拟卤化物386
Pseudohalogen and Pseudohalide 386
第13章 氧族元素 390
Chapter 13 The Oxygen Family Elements 390
13.1 氧及其化合物391
Oxygen and Its Compounds 391
13.2 硫及其化合物398
Sulfur and Its Compounds 398
13.3 硒分族407
The Selenium Subgroup 407
第14章 氮族元素 412
Chapter 14 The Nitrogen Family Elements 412
14.1 氮及其化合物413
Nitrogen and Its Compounds 413
14.2 磷及其化合物423
Phosphorus and Its Compounds 423
14.3 砷分族430
The Arsenic Subgroup 430
第 15 章 碳族元素 436
Chapter 15 The Carbon Family Elements 436
15.1 碳及其化合物437
Carbon and Its Compounds 437
15.2 硅及其化合物445
Silicon and Its Compounds 445
15.3 锗分族450
The Germanium Subgroup 450
第16章 硼族元素 455
Chapter 16 The Boron Family Elements 455
无 机 化 学
16.1 硼及其化合物456
Boron and Its Compounds 456
16.2 铝及其化合物466
Aluminum and Its Compounds 466
16.3 镓分族470
Gallium Subgroup 470
16.4 盐的水解的讨论474
Discussion of Salt Hydrolysis 474
第17章 铜、锌分族476
Chapter 17 The Copper Subgroup and Zinc Subgroup 476
17.1 铜分族476
The Copper Subgroup 476
17.2 锌分族484
The Zinc Subgroup 484
第18章 过渡元素(I)492
Chapter 18 The Transition Elements(I) 492
18.1 钛分族495
The Titanium Subgroup 495
18.2 钒分族502
The Vanadium Subgroup502
18.3 铬分族507
The Chromium Subgroup 507
18.4 锰分族516
The Manganese Subgroup 516
第19章 过渡元素(Ⅱ) 526
Chapter 19 The Transition Elements(Ⅱ) 526
19.1 铁系元素526
The Ferrous Elements 526
19.2 铂系元素538
The Platinum Elements 538
第20章 镧系元素和钢系元素 545
Chapter 20 The Lanthanides and Actinides 545
20.1 镧系元素545
目次
The Lanthanides 545
20.2 铜系元素560
The Actinites 560
Appendix1 An Element Crossword 568
Appendix 2 Thermodynamic Properties of Some Selected Inorganic
Compounds 572
Appendix 3 Standard Half-Cell Reduction Potentials of Selected
Elements 589
Appendix 4 Charge Densities of Selected lons 593
Appendix 5 Selected Bond Energies 596
Appendix 6 Ionization Energies of Selected Metals 598
Appendix 7 Electron Affinities of Selected Nonmetals 600
Appendix 8 Electronegativities of Selected Elements 601
Appendix 9 Selected Lattice Energies 602
Appendix 10 Selected Hydration Enthalpies 603
Appendix 11 Selected Ionic Radii 604
Appendix 12 Vapor Pressure of Water at Various Temperatures 605
Appendix 13 Boiling Point Elevation and Freezing Point Depression
Constants 606
Appendix 14 Enthalpies of Combustion for Some Selected OrganicCompounds 607
Appendix 15Dissociation Constants of Weak Acids and Bases 608
Appendix 16 Solubility Product Constants of Selected Slightly Electrolytes 609
Appendix 17 Formation Constants of Some Selected Complex lons in
Aqueous Solution 610
Appendix 18 Physical and Chemical Constants 611
元素周期表612